Product ID:REZ-RUSTIC MIXING BASE, 77-417
MSDS Date:11/25/1992
FSC:8010
NIIN:00N053111
MSDS Number: BVVLT

PPG INDUSTRIES INC

4325 ROSANNA DRIVE
ALLISON PARK, PA 15101
US

Emergency Phone: 304-843-1300

Info Phone: 412-492-5555

Cage: 47695

PPG INDUSTRIES INC

PITTSBURGH, PA 15272 US

Telephone: 1-800-245-2974 (CAL HYPO)

Cage: 47695

PHOSPHORIC ACID, TRIBUTYL ESTER; (TRIBUTYL PHOSPHATE)

CAS: 126-73-8

RTECS: TC7700000

Fraction By Weight: 1.2%

OSHA PEL 5 MG/M3

ACGIH TLV: 0.2 PPM

DIATOMACEOUS EARTH, FLUX-CALCINED

CAS: 68855-54-9

Fraction By Weight: 2-5%

OSHA PEL 6 MG/M3 (MFR)

ACGIH TLV: 6 MG/M3 (MFR)

DIATOMACEOUS EARTH, FLUX-CALCINED

CAS: 68855-54-9

Fraction By Weight: 5-10%

OSHA PEL 6 MG/M3 (MFR)

ACGIH TLV: 6 MG/M3 (MFR)

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 70-75%

OSHA PEL N/K

ACGIH TLV: N/K

ETHYLENE GLYCOL (SARA III)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 2-5%

ACGIH TLV: C 50 PPM,VAPOR

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

FILM FORMERS ROSINS, AND ADDITIVES

Fraction By Weight: 10-15%

OSHA PEL N/K

ACGIH TLV: N/K

SILICA, CRYSTALLINE - QUARTZ

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 2-5%

OSHA PEL 10 MG/M3 RDUST; Z-3

ACGIH TLV: 0.1 MG/M3 RDUST

SILICA, CRYSTALLINE - CRISTOBALITE

CAS: 14464-46-1

RTECS: VV7325000

Fraction By Weight: 2-5%

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 0.05 MG/M3 RDUST

FEEDING STUDY, ADVERSE LIVER & BLADDER EFTS

RTECS: 9999999ZZ

WHICH MAY CAUSE KIDNEY & LIVER DMG & WHICH HAS BEEN

RTECS: 9999999ZZ

OF THESE EFTS HAS BEEN FOUND IN HUMANS. THIS PROD

RTECS: 9999999ZZ

ASSOC W/INCREASED RISK OF CANCER IN LAB ANIMALS.

RTECS: 9999999ZZ

LEAD TO DISABLING INJURY KNOWN AS SILICOSIS. THESE

RTECS: 9999999ZZ

APPLIC OF THIS PROD IS NOT EXPECTED TO GENERATE

RTECS: 9999999ZZ

HAZARD FOR HUMANS IS LIMITED.

RTECS: 9999999ZZ

& TO REMOVE DECOMP PROD DURING WELDING/FLAME CUTTING.

RTECS: 9999999ZZ

OF NITRILE, NEOPRENE, OR LATEX

RTECS: 9999999ZZ

SHIELD WHEN POSSIBILITY EXISTS FOR EYE CONT DUE TO

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGEST:HARMFUL/FATAL IF
SWALLOWED. EYE:CAUSES EYE IRRIT. REDNESS, ITCHING, BURNING
SENSATION & VISUAL DISTURB MAY INDICATE EXCESSIVE EYE CONT.
SKIN:CAUSES PRIMARY SKIN IRRIT. DRYNESS, ITCHING, C RACKING,
BURNING, REDNESS, & SWELLING ARE CNDTNS ASSOC W/EXCESSIVE SKIN
CONT. INHAL:VAP & SPRAY MIST (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC MONO,
SUPPLEMENT. VOL 7, PG 341, 1987:GROUP 2A. NTP 6TH ANNUAL RPT ON
CARCIN, (SUPDAT)
Effects of Overexposure:HLTH HAZ:MAY BE HARMFUL IF INHALED. VAP
GENERATED @ ELEVATED TEMP IRRITATES EYES, NOSE & THROAT. SANDING &
GRINDING DUSTS MAY BE HARMFUL IF INHALED. CHRONIC:AVOID LONG TERM &
RPTD CONT. TRIBUTYL PHOSP HATE HAS BEEN SHOWN TO CAUSE ADVERSE NERV
SYS EFTS IN LAB ANIMALS EXPOS BY INGEST/INJECT INTO BODY. IN
SEPARATE (ING 9)

First Aid:INGEST:DO NOT INDUCE VOMIT. EYE:FLUSH IMMED W/PLENTY OF WATER
FOR @ LEAST 15 MINS. SKIN:FLUSH IMMED W/PLENTY OF WATER FOLLOWED BY
WASHING W/SOAP & WATER. INHAL:IF AFFECTED BY INHAL OF VAP/SPRAY
MIST, REMOVE TO FRESH AIR. APPLY ARTF RESP & OTHER SUPPORTIVE
MEASURE REQD. OTHER:IF INGEST, ANY TYPE OF OVEREXP/SYMP OF OVEREXP
OCCUR DURING/FOLLOWING USE OF PROD, CONT POIS CTL CTR, EMER
ROOM/PHYS IMMED.

Flash Point Method:PMCC
Extinguishing Media:USE NFPA CLASS B EXTING (CO*2, DRY CHEM/UNIVERSAL
AQUEOUS FILM FORMING FOAM) DESIGNED TO EXTING NFPA CLASS (SUPDAT)
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFTIVE. WATER SPRAY MAY BE USED TO COOL CLSD
CNTNRS TO PVNT PRESS BUILD-UP & FOG (SUPDAT)
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE OR BURST (DUE TO
BUILD-UP OF STEAM PRESS) WHEN EXPOSED TO EXTREME HEAT.

Spill Release Procedures:PROVIDE MAX VENT. ONLY PERS EQUIPPED W/PROPER
RESP & SKIN & EYE PROT SHOULD BE PERMITTED IN AREA. REMOVE ALL
SOURCES OF IGNIT. TAKE UP SPILLED MATL W/SAWDUST, VERMICULITE, OR
OTHER ABSORB MATL & PLACE INTO CNTNRS. FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE ABOVE 120 DEGREES F.
STORE LG QTYS IN BUILDING DESIGNED & PROTECTED FOR STOR OF NFPA
CLASS IIIB COMBUST LIQ. PROT FROM FREEZING.
Other Precautions:IF THIS MATL IS PART OF MULTIPLE COMPONENT SYS, READ
MATL SFTY DATA SHEET(S) FOR OTHER COMPONENT/COMPONENTS BEFORE
BLENDING AS THE RESULTING MIXTURE MAY HAVE THE HAZARDS OF ALL OF
ITS PARTS.

Respiratory Protection:WHERE VENTILATION IS INADEQUATE, USE NIOSH/MSHA
APPROVED SUITABLE RESPIRATOR.
Ventilation:PROVIDE GEN DILUTION/LOC EXHAUST VENT IN VOL & PATTERN TO
KEEP CONC OF INGREDS BELOW LOWEST SUGGESTED EXPOS LIM,(ING 16)
Protective Gloves:IMPERMEABLE GLOVES CONSTRUCTED (ING 17)
Eye Protection:CHEM TYPE SPLASH GOGG&FULL FACE(ING 18)
Other Protective Equipment:IMPERMEABLE APRON. CLEAN OR DISCARD CONTAMD
CLOTHING & SHOES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXTING MEDIA:IIIB COMBUST LIQ FIRES. FIRE FIGHT PROC:NOZZ ARE PREF.
FIRE-FIGHTERS SHOULD WEAR NIOSH/MSHA APPRVD SCBA. EXPLAN OF
CARCIN:1991:ANTIC TO BE CARCIN. SILICA,
CRYSTALLINE-CRISTOBALITE:IARC MO NO, SUPPLEMENT, VOL 7, PG 341,
1987:GROUP 2A. NTP 6TH ANNUAL PRT ON CARCIN, 1991:ANTIC TO BE
CARCINOGEN.

Boiling Pt:B.P. Text:>205F,>96C
Vapor Pres:17.2 MM
Vapor Density:HVR/AIR
Spec Gravity:1.08
Evaporation Rate & Reference:34 (BUOAC=100)
Solubility in Water:75.3%
Appearance and Odor:VISCOUS LIQ W/ODOR CHARACTRISTIC OF CHEM FAMILY &
ANY SOLV LISTED IN INGREDS
Percent Volatiles by Volume:79.70

Stability Indicator/Materials to Avoid:YES
AVOID CONT W/STRONG ALKALIES, STRONG MINERAL ACIDS, OR STRONG OXIDIZING
AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY PRODUCE HAZ DECOMP PRODUCTS WHEN
HEATED. WELDING, BRAZING, OR CARBON MONOXIDE, FORMALDEHYDE.

Waste Disposal Methods:WASTE MATL MUST BE DISPOSED OF I/A/W FEDERAL,
STATE, PROVINCIAL, AND LOC ENVIRON CONTROL REGS. EMPTY CNTNRS
SHOULD BE RECYCLED/DISPOSED OF THRU AN APPRVD WASTE MANAGEMENT
FACILITY.

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particular situation.